Rydberg Equation Calculator

Our Rydberg equation calculator is a tool that helps you compute and understand the hydrogen emission spectrum. You can use our calculator for other chemical elements, provided they have only one electron (so-called hydrogen-like atom, e.g., He⁺, Li²⁺ , or Be³⁺).

Read on to learn more about different spectral line series found in hydrogen and about a technique that makes use of the emission spectrum. In the below text, you will also find out what the Rydberg formula is.

We know from the Bohr model that electron orbits around the nucleus only at specific distances, called energy levels n (n > 0 and is an integer).

When an electron drops to a lower orbit (n decreases), it emits an electromagnetic wave (photon) of a particular wavelength corresponding to the change of the electron's energy.

There are many possible electron transitions in an atom, and the collection of those transitions makes up an emission spectrum, which is unique for each element. In hydrogen, we obtain different series:

• Lyman series, when an electron goes from n ≥ 2 to n = 1 energy level;

• Balmer series, when an electron goes from n ≥ 3 to n = 2 energy level;

• Paschen series, when an electron goes from n ≥ 4 to n = 3 energy level;

• Brackett series, when an electron goes from n ≥ 5 to n = 4 energy level;

• Pfund series, when an electron goes from n ≥ 6 to n = 5 energy level; and

• Humphreys series, when an electron goes from n ≥ 7 to n = 6 energy level.

The specific wavelengths of emitted light could be predicted with the following Rydberg formula:

where:

• $\lambda$ – Wavelength of emitted light (in a vacuum);
• $Z$ – Atomic number (for hydrogen, $\small Z = 1$);
• $n_1$ – Principal quantum number of the initial state (initial energy level);
• $n_2$ – Principal quantum number of the final state (final energy level); and
• $R$ – Rydberg constant for hydrogen $\small R ≈ 1.0973 \times 10^7\ \rm m^{-1}$.

In the advanced mode of our Rydberg equation calculator, you can compute the frequency and energy of the emitted electromagnetic wave. If you want to know how to convert wavelength to energy or frequency, check our photon energy calculator.

The study of the interaction between matter and an electromagnetic wave is called spectroscopy. It is a very helpful technique currently used in many areas of science. We can distinguish three main types of spectroscopy:

• Emission spectroscopy in which we measure the energy of photons released by the material. Emissions can also be induced by other sources, e.g., flames, sparks, or electromagnetic waves. Our Rydberg equation calculator is dedicated to this type of spectroscopy.

• Absorption spectroscopy occurs when we pass photons through the material and observe which photon's energies were absorbed.

• Reflection spectroscopy in which we determine how incident photons are reflected or scattered by the material.